tert-Butyl methyl ether(MTBE)


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  • tert-Butyl methyl ether(MTBE)
  • 1634-04-4
  • C5H12O
  • 88.1497
  • Clear colorless liquid
Inquiry

Manufacturer supply good quality tert-Butyl methyl ether(MTBE) 1634-04-4 with stock

  • Molecular Formula:C5H12O
  • Molecular Weight:88.1497
  • Appearance/Colour:Clear colorless liquid 
  • Vapor Pressure:251mmHg at 25°C 
  • Melting Point:-110 °C 
  • Refractive Index:n20/D 1.369(lit.)  
  • Boiling Point:55.2 °C at 760 mmHg 
  • Flash Point:-27 °F 
  • PSA:9.23000 
  • Density:0.75 g/cm3 
  • LogP:1.43130 

Methyl tert-butyl ether(Cas 1634-04-4) Usage

General Description

Methyl tert-butyl ether (MTBE) is a volatile organic compound that is used as a fuel additive to increase octane rating and reduce carbon monoxide and ozone levels in gasoline. It is highly flammable and has a characteristic odor similar to that of diethyl ether. MTBE has been found to be a significant groundwater contaminant due to its high solubility in water and resistance to microbial degradation, leading to concerns about its potential health and environmental impacts. Despite its widespread use, MTBE has been banned in several states and countries due to its potential hazards and environmental persistence.

InChI:InChI=1/C5H12O/c1-5(2,3)6-4/h1-4H3

1634-04-4 Relevant articles

Heteropoly Acids Supported on Acidic Ion-exchange Resin as Highly Active Solid-acid Catalysts

Baba, Toshihide,Ono, Yoshio,Ishimoto, Tadao,Moritaka, Shun-ichi,Tanooka, Seiichi

, p. 2155 - 2156 (1985)

Heteropoly acids supported on a macroret...

-

Cohen,Schneider

, p. 3382,3386 (1941)

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Activity of Polymeric and Zeolite-Containing Catalysts in Production of Methyl tert-Butyl Ether

Koval',Bazhina,Safronova,Perevezentsev,Kosukhin,Erofeev,Ryabov

, p. 71 - 73 (2001)

The effect of structural and acid charac...

High-pressure heat-flow calorimeter. Determination of the enthalpy of reaction for the synthesis of methyl t-butyl ether from methanol and 2-methylpropene

Arntz, H.,Gottlieb, K.

, p. 967 - 972 (1985)

A high-pressure heat-flow calorimeter su...

Gas phase synthesis of MTBE on triflic-acid-modified zeolites

Nikolopoulos,Kogelbauer,Goodwin Jr.,Marcelin

, p. 76 - 82 (1996)

The gas phase synthesis of MTBE (methyl ...

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Barton,D.H.R. et al.

, p. 1466 (1970)

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Gas phase synthesis of MTBE from methanol and isobutene over dealuminated zeolites

Collignon,Mariani,Moreno,Remy,Poncelet

, p. 53 - 66 (1997)

Gas phase synthesis of MTBE from methano...

On Anchimerically Assisted Homolysis via Sulphide Functions

Lawson, Alexander J.

, p. 1238 - 1239 (1981)

In contrast to O-O fission, anchimeric a...

Determination of adsorption and kinetic parameters for methyl tert-butyl ether synthesis from tert-butyl alcohol and methanol

Ray,Ziyang,Hidajat

, p. 209 - 221 (2001)

Synthesis of MTBE by direct reaction bet...

Kinetics of liquid phase synthesis of methyl tert-butyl ether from tert-butyl alcohol and methanol catalyzed by ion exchange resin

Matouq,Goto

, p. 825 - 831 (1993)

Synthesis of methyl tert-butyl ether (ab...

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Waldron,Snyder

, p. 3059 (1973)

-

-

Saenger,v. Sonntag

, p. 5489,5501 (1970)

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Strong influence of the polyanion structure on the secondary structure of solid heteropolyacids and their catalytic activity; methyl tert-butyl ether synthesis in the pseudo-liquid phase of heteropolyacids

Shikata, Sawami,Misono, Makoto

, p. 1293 - 1294 (1998)

It has been shown that the high catalyti...

Catalysis in a porous molecular capsule: Activation by regulated access to sixty metal centers spanning a truncated icosahedron

Kopilevich, Sivil,Gil, Adria,Garcia-Rates, Miquel,Bonet-Avalos, Josep,Bo, Carles,Mueller, Achim,Weinstock, Ira A.

, p. 13082 - 13088 (2012)

The 30 cationic {MoV2O4(acetate)} + unit...

-

Stevens,Deans

, p. 290 (1939)

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Coadsorption of methanol and isobutene on HY zeolite

Kogelbauer,Goodwin,Lercher

, p. 8777 - 8781 (1995)

In order to develop a better understandi...

Liquid phase synthesis of MTBE from methanol and isobutene over acid zeolites and Amberlyst-15

Collignon,Loenders,Martens,Jacobs,Poncelet

, p. 302 - 312 (1999)

The liquid phase synthesis of methyl ter...

Development of the Late-Phase Manufacturing Process of ZPL389: Control of Process Impurities by Enhanced Process Knowledge

Santandrea, Ernesto,Waldraff, Christine,Gerber, Gilles,Moreau, Ma?l,Beney, Pascal

, p. 1190 - 1205 (2021/05/06)

The development of the late-phase manufa...

Reactivity and Product Analysis of a Pair of Cumyloxyl and tert-Butoxyl Radicals Generated in Photolysis of tert-Butyl Cumyl Peroxide

Oyama, Ryoko,Abe, Manabu

, p. 8627 - 8638 (2020/07/21)

Alkoxyl radicals play important roles in...

Catalytic etherification of alcohols in Shilov system: C[sbnd]O versus C[sbnd]H bond activation

Khazipov, Oleg V.,Nykytenko, Denys V.,Krasnyakova, Tatyana V.,Vdovichenko, Alexander N.,Fuentes Frias, Dario A.,Mitchenko, Serge A.

, p. 490 - 498 (2016/12/16)

A novel catalytic reaction of alcohol et...

A METHOD FOR CO-PRODUCING ISOBUTENE AND METHYL TERT-BUTYL ETHER BY USING TERT-BUTANOL MIXTURE

-

Page/Page column 12, (2016/10/08)

This invention describes a method for co...

1634-04-4 Process route

tert-butyl cumyl peroxide
3457-61-2

tert-butyl cumyl peroxide

ethane
74-84-0

ethane

tert-butyl methyl ether
1634-04-4

tert-butyl methyl ether

1-methyl-1-phenylethyl alcohol
617-94-7

1-methyl-1-phenylethyl alcohol

acetophenone
98-86-2

acetophenone

acetone
67-64-1

acetone

<i>tert</i>-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
Conditions Yield
With air; In [D3]acetonitrile; at 22 ℃; for 1h; UV-irradiation; Inert atmosphere;
tert-butyl cumyl peroxide
3457-61-2

tert-butyl cumyl peroxide

methanol
67-56-1

methanol

ethane
74-84-0

ethane

tert-butyl methyl ether
1634-04-4

tert-butyl methyl ether

1-methyl-1-phenylethyl alcohol
617-94-7

1-methyl-1-phenylethyl alcohol

acetophenone
98-86-2

acetophenone

acetone
67-64-1

acetone

<i>tert</i>-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
Conditions Yield
With oxygen; In [D3]acetonitrile; at 22 ℃; for 1h; UV-irradiation; Inert atmosphere;

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1634-04-4 Downstream products

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    Ethylene glycol di-tert-butyl diether

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    tri-tert-butyl glycerol ether

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